Hi guys just an update; solved!
I parked the vehicle level and checked for a leak - heater valve was cracked and leaked coolant from there. However, upon replacing this I decided to do a service. Whilst removing the spark plugs, they broke in place leaving behind the thread on the cylinder head - guess from the over heating, I was able to remove 2 successfully. I attempted to remove the broken threads using an ez out, the first was successful. The second attempt broke the ez out . Cylinder head removal time. I ended up doing a complete cylinder head gasket replacement including all other oil seals, gaskets and water pump. Found a load of sludge stuck in the timing chain cover and areas below the oil filter - note the oil that I removed from the sump was clear and had no signs of oil and coolant mixed. Proof that the first guy who worked on this vehicle did not do his job correctly. I used an air compressor with an oil can and petrol and blew out every single oil crevice I could find around the timing chain cover area. Put everything back together, started and runs like a dream.
Thank you guys for the help. It was exciting for me as this was one of the first cylinder head gasket replacements I've done even though I thought this would be a much easier fix initially.