I think cpt1910 is referring to jamming, rather than blocking.
Jamming probably has some intricate legal/red tape issues.
Blocking, as in shielding, however is (should be) ok.
I know of film that is mostly used in cars to block infrared from the sun, called siglasol. It also blocks rf, but then you need to have the walls made of steel or something that blocks the signal. Any openings, even very small ones, can leak signal through.
I am not sure how efficiently siglasol blocks rf though.
If the designated area is not completely closed off, then there will be a "grey" area where reception is possible with mixed success.