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what are you outgoing email settings? Maybe you've missed an encryption or something (especially if you are using gmail)
The settings are synced with my e-mail settings on my Mac. I have checked them and they are correct. I have also tried setting up an account manually, but still no good. By the way, I have a M-web account
Are you connecting via the mweb account (ie. through the sync connection), or via GPRS/3G to the net?
E-mail : Configuring your iPhone
Important: E-mail setup on an iPhone differs from any other cellphone. Please only use the instructions on this page to set up your iPhone or iPod Touch to manage your MWEB e-mail.