Lupus
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Actually no that's incorrect, most of the time people are at work during the day they are not at home using their appliances and such, but around 5pm or so they are and that's when it peaks.Max load is during the day. Always is, always will be. We live in the day, and use most of the power when we're awake (and working). Duck curve at the end of the day for the evening peak.
If I could find some load graphs, I'd post. Link if you can find, my googlefu betrays me today.
Typically load is low in morning, highest daytime, then slopes off again.
There is an evening peak at around 7pm tailing off to 9pm (cooking and heating mostly), then it basically dies till the morning again.
Adding decent amounts of solar and/or wind in a country where both wind and solar generation are the best in the world is not a hard decision.
Storage is not quite necessary here yet, although it would be nice.
We're better off adding a lot more generation.

Here's todays power alert from Eskom where it has it's forecast avaliability vs the demand forecast and the max availability, look at how the load slowly increases over the course of the day with a peak around 6pm. Now solar would alleviate the time period from 6am to 6pm, but it won't do anything for 6pm.
Here's an older one from the UK

Notice a similar trend here.
Edit:
They even have power stations for peak periods
Peaking power plant - Wikipedia
"
Renewable energy[edit]
For countries that are trending away from coal-fired base load plants and towards intermittent energy sources such as wind and solar, there is a corresponding increase in the need for peaking or load following power plants and the use of grid interties, such as the WECC Intertie Paths."
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