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It will automatically use the 3G.
Local connection gets priority over a networked connection. There are however ways to change all of that...
do you know if there is any software out there that can block 3G connections when automatically connecting to a LAN? We have laptop users that are blocked from accessing specific sites, however they then plug in their 3G card and surf, whilst still on the corporate network.
how would you also change the priority?
1. Click the Start Button
2. Right Click "Network" and then left Click Properties
3. From the "Network And Sharing Center" window click "Change Adapter Settings"
4. On the "Network Connections" window, press the ALT key on your keyboard to being up the menu bar
5. Click the "Advanced" menu and then "Advanced Settings"
6. In the "Advanced Settings" window you will see the "Adapters and Bindings" tab and under "Connections" you will see the order they are in, you can use the arrows to the side to move the connection priority up and down.
If you're on windows 7 the following may be relevant,