derp I hadn't realized, you were talking about the plane the panel sits on , and not the direction of the normal of the panel's plane
90-25 = 65 as I simulated, so we are in agreement
What you call roof pitch, I am familiar with calling zenith, with elevation being the difference between zenith and a right angle (elevation being elevation above the horizon).
The reason for the distinction between zenith and elevation is that zenith takes into account azimuth, and is therefore the minimum angle between the face of the panel (vector normal to the plane the panel sits on) and the vector of the sun's apparent location relative to a flat and plumb plane on the ground