My apologies. I see that there are 2 different types of batteries available to car manufacturers. Series and parallel types.
A 12V lead acid, automotive battery is always wired in series internally.
It is impossible to produce a single cell 12V lead acid battery otherwise you'd be defying the laws of chemistry. A single cell can only ever produce 2.1V using lead and sulphuric acid.
Larger vehicles like trucks may have multiple 12V or 24V (12 cells in series) batteries wired in parallel but the individual batteries have cells wired in series.
http://en.wikipedia.org/wiki/Automotive_battery