So is highest voltage with lowest amp always preferable from an efficiency point of view ignoring the cost of the cabling?
the max amp is 8.78 so with 4 panels I would be under the max of 40A of my inverter.
When dealing with charge controllers, you need to be far more concerned with voltage than amps. Many charge controllers will reduce the amps because it's easy to do, but voltage is more complex to reduce. I am not saying that your charge controller is capable of doing this though, just something to bear in mind.
The optimal (most efficient) voltage for your charge controller is between 30 and 80V DC. It makes sense to use a higher voltage (like 75V) rather than a lower voltage (like 37V) because 1) there is less voltage drop at higher voltages and 2) you need to consider startup voltage in the early morning / late afternoon, as well as on cloudy days.
So I could get higher than the vmp of the panel?
Yes. I have seen evidence of an array rated at 5.88kWp pushing 7.79kW, with a cool coastal breeze blowing across it.

I guess that you missed this:
Always size the max voltage at VoC, remember that the specs are usually given at STC which is 25 degrees, and temperature drop will increase voltage.
I did not know that. So am I cutting it too close with the panels I had looked at? Would I be better off running 420w panels in parallel that have 40v vmp and 47v voc?
I am not sure, because the panel you linked to does not have a proper spec sheet. Most panels come with a spec sheet, like this:
Looking at the column for a 535W Longi panel, you will see that the Voc voltage is 49.35 volts. You will also see that the Temperature Coefficient of Voc is -0.27% (at STC). This means that for every degree below STC, the panel will produce 0.134232 volts more. If you live in a area with cold mornings / evenings, or with cooling coastal breezes, this could be about, say 20 degrees. That's about 2.55 volt more per panel, and if you have a string of 8 of them in series, 20.4 volts. Also be careful, because some panel specs give the temp coefficient at NOCT (45 degrees), not STC.
A good step by step string sizing guide is
here.