One can do this, but as has been mentioned several times, the USB standard is designed around providing a maximum of 500mA. If you connect something straight to the a computer PSU, and the device's electronics up to scratch, you can have 25A flowing through your device, which is not great.
Depending on the circuitry inside your USB Hubs that you currently have, you might be able to get away with putting a beefier PS, or event a computer's PSU onto it, if the Hub's electronics handle the overcurrent issue.
If you have AC chargers for all of the tablets, I really think using them is your best bet. These (see below) are the best devices ever, allow for plugging in two europlugs per standard 3 prong output. Get 3x 6 plug multiplugs, and ample of these adaptors and you're good to go.