Have you tried changing the Flash sync speed for Av from Auto to fixed 1/200?It's a stupid thing on Canon cameras AFAIK (even though Koffie loves it). In Av, the camera tries to set the exposure for the background. From 40d's manual:
To get around this, I always use M for flash photography.
EDIT or just shooting P when using the flash?
A nice article on Canon and flash - http://photonotes.org/articles/eos-flash/
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