OK, this is how I ran a similar setup at work for a couple of years without any problems. The extra battery pack (12V or 24V depending on your UPS) is connected in parallel to the UPS internal pack via the normally open contacts of a 220 Volt relay. The relay is fed from the mains supply, thus as long as there is mains the extra batteries are disconnected from the UPS internal battery pack. The ups chargers its own battery pack and the external pack is connected to a separate charger. When the mains fails the relay drops out and connects the external pack to the internal pack and Bob's your Auntie.
Show that to your electrician
Take old bateries with

