Reviving an old thread here...
It appears that MTN has removed the geoblocking, I suspect due to some countries having completed their 2G and 3G shutdowns and MTN maybe not yet having VoLTE roaming enabled for all of their roaming partners. Their website
has been updated to show that Wi-Fi calling can now be used abroad (Android only though, iPhone users are out of luck but apparently this is imminent™).
Since I have an MTN prepaid SIM abroad that I keep active (for various legacy reasons, and also because having to go through RICA every time I come back for a visit is a proper pain in the arse), I've been testing this out over the past week. It didn't work initially, but after some emails back and forth between MTN and myself, it turned out that VoLTE wasn't provisioned for me on their end: once MTN sorted that out, both VoLTE roaming and Wi-Fi calling started working -- so, if Wi-Fi calling doesn't work for you, this is something worth checking.
What I did find interesting is MTN's roaming order of precedence and hand-off. The phone will choose whichever of VoLTE roaming or Wi-Fi calling is available (VoLTE roaming seems to be preferred if both are available) and then stubbornly stick to it until that option becomes unavailable. So, even if I'm within range of a Wi-Fi network, it will not switch to Wi-Fi calling if it is using VoLTE roaming, but if I switch to airplane mode to force it onto Wi-Fi calling and then disable it, it will stay on Wi-Fi calling indefinitely until I leave the range of the Wi-Fi network.
To force Wi-Fi calling to be always on, the workaround that I have found is to force the MTN SIM to 3G and lower. This works for me because all 2G and 3G networks in New Zealand were shutdown as of March 2026: your mileage may vary in a country that still has active 2G and 3G networks. Due to the 2G and 3G shutdown here, the effect is that the MTN SIM can no longer connect to any roaming partner, and thus it always uses Wi-Fi calling calling when I'm in range of a Wi-Fi network and routes through the data connection of my primary NZ SIM when I'm on the road.
Hope this helps someone.